Ensuring the safety of Large Language Models (LLMs) is critical for real-world deployment. However, current safety measures often fail to address implicit, domain-specific risks. To investigate this gap, we introduce a dataset of 3,000 annotated queries spanning education, finance, and management. Evaluations across 14 leading LLMs reveal a concerning vulnerability: an average jailbreak success rate of 57.8%. In response, we propose MENTOR, a metacognition-driven self-evolution framework. MENTOR first performs structured self-assessment through simulated critical thinking, such as perspective-taking and consequential reasoning to uncover latent model misalignments. These reflections are formalized into dynamic rule-based knowledge graphs that evolve with emerging risk patterns. To enforce these rules at inference time, we introduce activation steering, a method that directly modulates the model's internal representations to ensure compliance. Experiments demonstrate that MENTOR substantially reduces attack success rates across all tested domains and achieves risk analysis performance comparable to human experts. Our work offers a scalable and adaptive pathway toward robust domain-specific alignment of LLMs.

Vision-Language-Action (VLA) models are driving rapid progress in robotics by enabling agents to interpret multimodal inputs and execute complex, long-horizon tasks. However, their safety and robustness against adversarial attacks remain largely underexplored. In this work, we identify and formalize a critical adversarial vulnerability in which adversarial images can "freeze" VLA models and cause them to ignore subsequent instructions. This threat effectively disconnects the robot's digital mind from its physical actions, potentially inducing inaction during critical interventions. To systematically study this vulnerability, we propose FreezeVLA, a novel attack framework that generates and evaluates action-freezing attacks via min-max bi-level optimization. Experiments on three state-of-the-art VLA models and four robotic benchmarks show that FreezeVLA attains an average attack success rate of 76.2%, significantly outperforming existing methods. Moreover, adversarial images generated by FreezeVLA exhibit strong transferability, with a single image reliably inducing paralysis across diverse language prompts. Our findings expose a critical safety risk in VLA models and highlight the urgent need for robust defense mechanisms.